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1 article(s) from Sarter, Christopher

The role of alkyl substituents in deazaadenine-based diarylethene photoswitches

Christopher Sarter,
Michael Heimes and
Andres Jäschke

Beilstein J. Org. Chem. 2016, 12, 1103–1110, doi:10.3762/bjoc.12.106

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Figure 1: Diarylethene photoswitches. A: classical design and photoisomerization reaction [27]. B: purine-based p...

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Scheme 1: Synthesis of 7-deaza-2’-deoxyadenosine photoswitches with one and two methyl groups via Suzuki cros...

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Scheme 2: Optimized route for synthesis of 7-deaza-7-iodo-8-methyl-2’deoxyadenosine (9).

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Scheme 3: Synthesis of the boronic acid pinacolate esters.

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Figure 2: Spectral changes of the pyridyl switch with one (1b) and two (2b) methyl groups upon irradiation wi...

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Figure 3: Reversibility measurements of deazaadenosine photoswitches with one and two methyl groups. A 60 µM ...

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Figure 4: Stability analysis of compounds 1b–d and 2b–d upon different times of UV irradiation, monitored by ...

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Figure 5: Thermostability measurements of the 7-deazaadenosine nucleosides. A 60 µM solution of the compound ...

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Published 01 Jun 2016

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